Detailed Solution:
The correct answer is “Nitrochloroform”.
Nitrochloroform is not an explosive matter. While it is a highly toxic and dangerous chemical, it does not possess the necessary properties to undergo an explosive reaction.
The other options listed - Trinitrotoluene (TNT), Dinitro glycerine, and Cyclo Trimethylene trinitrarmine (RDX) - are all well-known explosives.
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