Detailed Solution:
The correct answer is “the volume will first decrease and than increase”.
The volume will first decrease and than increase. This unique behavior of water is due to its anomalous expansion.
As the temperature decreases from 9°C to 4°C, the water molecules come closer together, and the volume decreases. However, from 4°C to 3°C, the water molecules start to form a crystalline structure (similar to ice), which occupies more space. Thus, the volume increases.